Akshually, worked on this stuff at RU. LMK if you need a technical dictionary or an interpreter. Me and
@RU848789 can draw pictures for you:
The effect of magnetic fields to 15T on the electrical resistance (R) of Bi-Sr-Ca-Cu-O superconductors has been measured at precise temperatures during the transition to the superconducting state. The results show that the temperature at which the externally-applied magnetic field causes a divergence of resistance (R) as a function of inverse temperature is approximately at the same temperature where the positive Hall coefficient begins its steep descent to zero. At slightly higher temperature the Hall coefficient shows a singularity peak akin to a delta function. Internal electric field calculations show that the structure of the superconducting oxides, having more than a single building block polyhedron, gives rise to strong electrostatic fields in the unit cell which in turn causes charge separation or polarization. The charge separation is in accord with the importance of high oxidation states of the multivalence cations and suggests the use of high oxygen overpressure during processing. The magnitude of Tc scales closely with the number of bound holes (associated with the charge transfer excitations) per unit cell. Extensive computer calculations using this model indicate attractive pairing of electrons at inter-electron separations of about 10–15A.
The perovskite structure in Pb(Zn1/3Nb2/3)O3 can be stabilized by the addition of Pb(Ni1/3Nb2/3)O3 and PbTiO3.Pb(Ni1/3Nb2/3)O3 assists in lowering the sintering temperature and shifting the Curie temperature of ceramics while PbTiO3 helps to optimize the dielectric properties. The phase stability and dielectric properties of several compositions in the Pb(Zn1/3Nb2/3)O3-Pb(Ni1/3Nb2/3)O3-PbTiO3 ternary relaxor ferroelectric system were investigated for possible capacitor applications. The effect of calcining and sintering temperature on the stability of perovskite phase in PZN rich compositions was studied extensively as a function of composition. The boundary line separating perovskite and mixed phases was determined for compositions near PZN. Several compositions can be sintered below 1050°C. The dielectric properties of compositions near the mixed phase boundary showed strong dependence on the percentage of pyrochlore phase. Compositions with a dielectric constant of 12.500 at room temperature have been identified which meet Z5T and Y5U specifications for dielectric constant and tan δ
